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Read e-book online Asymmetric Catalysis from a Chinese Perspective PDF

By Qi-Lin Zhou, Jian-Hua Xie (auth.), Shengming Ma (eds.)

Qi-Lin Zhou and Jian-Hua Xie: Chiral Spiro Catalysts.- Fuk Loi Lam, Fuk Yee Kwong and Albert S. C. Chan: Chiral Phosphorus Ligands with fascinating homes and sensible Applications.- Jiang Pan, Hui-Lei Yu, Jian-He Xu, Guo-Qiang Lin: Advances in Biocatalysis: Enzymatic Reactions and Their Applications.- Mei-Xiang Wang: Enantioselective Biotransformations of Nitriles.- guy relatives Wong, Yiu Chung Yip and Dan Yang: uneven Epoxidation Catalyzed by means of Chiral Ketones.- W. J. Liu, N. Li and L. Z. Gong: uneven Organocatalysis.- Qing-Hua Fan and Kuiling Ding: Enantioselective Catalysis with Structurally Tunable Immobilized Catalysts.- Chang-Hua Ding, Xue-Long Hou: Transition Metal-Catalyzed uneven Allylation.- Jian Zhou and Yong Tang: Enantioselective Reactions with Trisoxazolines.- Xiang-Ping Hu, Duo-Sheng Wang, Chang-Bin Yu, Yong-Gui Zhou, and Zhuo Zheng: experience in uneven Hydrogenation: Synthesis of Chiral Phosphorus Ligands and uneven Hydrogenation of Heteroaromtics.

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Millward DB, Sammis G, Waymouth RM (2000) J Org Chem 65:3902–3909 97. Zhang W, Wang L-X, Shi W-J, Zhou Q-L (2005) J Org Chem 70:3734–3736 98. Aubert C, Buisine O, Malacria M (2002) Chem Rev 102:813–814 99. Ojima I, Tzamarioudaki M, Li Z, Donovan RJ (1996) Chem Rev 96:635–662 100. Buchwald SL, Hicks FA (1999) In: Jacobsen EN, Pfaltz A, Yamamoto H (eds) Comprehensive asymmetric catalysis, vol 2, Springer, Berlin, p 491–510 101. Fan B-M, Xie J-H, Li S, Tu Y-Q, Zhou Q-L (2005) Adv Synth Catal 347:759–762 102.

Thus, under identical conditions, optically pure 17 was obtained from the hydrogenation of the corresponding enantiomer of 16 [11]. 2 Development of BisbenzodioxanPhos Ligand Built upon the success of P-Phos and other related heteroaromatic phosphine ligands, we turned to the development of a new type of chiral ligand, BisbenzodioxanPhos [12], which was independently synthesized by Genêt et al. and was named SynPhos by these authors [13]. BisbenzodioxanPhos bears a bis-benzodioxane scaffold, a structural feature similar to that H8-BINAP.

Reported that chiral spiro organoiodine(III) derived from enantiopure SPINOL is an efficient chiral reagent for enantioselective oxidative dearomatization of phenols to construct chiral ortho-spirolactones [118]. These essential experiments further expand the application of spirobiindane-based chiral ligands/reagents in asymmetric synthesis. 4]nona-1,6-diene backbone have been reported by Ding et al. [119]. The SpinPHOX ligands were successfully applied in Ir-catalyzed asymmetric hydrogenation of imines, providing chiral amines with excellent enantioselectivities (up to 98% ee).

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